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Article Dans Une Revue Organic & Biomolecular Chemistry Année : 2018

A convenient synthetic route towards 1-hydroxymethylene-1,1- bis(H-phosphinates)

Résumé

A practical general route to 1-hydroxymethylene-1,1-bis(H-phosphinates) has been developed. Diverse alkyl or (hetero)aryl bisphosphinates were rapidly obtained in satisfying to excellent yields from corresponding acid chlorides and in situ generated bis(trimethylsilyl)phosphonite. This work is complementary to previous approaches. A generalisable procedure was optimised allowing the description of numerous compounds. To check the literature data, a pka value study was also performed.

Domaines

Chimie organique
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Dates et versions

hal-02468919 , version 1 (06-02-2020)

Identifiants

Citer

Jade Dussart, Nicolas Guedeney, Julia Deschamp, Maelle Monteil, Olivier Gager, et al.. A convenient synthetic route towards 1-hydroxymethylene-1,1- bis(H-phosphinates). Organic & Biomolecular Chemistry, 2018, 16 (38), pp.6969-6979. ⟨10.1039/C8OB01878B⟩. ⟨hal-02468919⟩
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